Atom vs Compound

An atom contains one single nucleus with its protons and neutrons within and electrons around the nucleus. A compound or molecule involves more than one atom to make a species.

In ordinary chemical reactions, the nucleus of each atom (and thus the identity of the element) remains unchanged. Electrons, however, can be either transferred (added or lost) between atoms (ionic bonding) or shared between atoms (covalent bonding). Ionic bonds are electrostatic forces of attraction, that is, the attractive forces experienced between objects of opposite electrical charge (in this case, cations and anions). Covalent bonds are the sharing of electrons through the attractive forces between the positively charged nuclei of the bonded atoms and one or more pairs of electrons that are located between the atoms. Compounds are classified as ionic or molecular (covalent) on the basis of the bonds present in them.

In ionic bonding, the atoms that gain or lose electron(s) form electrically charged particles called ions see below.

Figure A shows a sodium atom, N a, which has a nucleus containing 11 protons and 12 neutrons. The atom’s surrounding electron cloud contains 11 electrons. Figure B shows a sodium ion, N a superscript plus sign. Its nucleus contains 11 protons and 12 neutrons. The ion’s electron cloud contains 10 electrons and is smaller than that of the sodium atom in figure A.
(a) A sodium atom (Na) has equal numbers of protons and electrons (11) and is uncharged. (b) A sodium cation (Na+) has lost an electron, so it has one more proton (11) than electrons (10), giving it an overall positive charge, signified by a superscripted plus sign.

The Periodic table is useful in being able to help predict the most common ion for a species. Atoms will usually lose or gain electron(s) to be like the closest noble gas (group 18). To learn more about why these are the common ions please check out the page on electron configurations.

Group one of the periodic table contains L i superscript plus sign in period 2, N a superscript plus sign in period 3, K superscript plus sign in period 4, R b superscript plus sign in period 5, C s superscript plus sign in period 6, and F r superscript plus sign in period 7. Group two contains B e superscript 2 plus sign in period 2, M g superscript 2 plus sign in period 3, C a superscript 2 plus sign in period 4, S r superscript 2 plus sign in period 5, B a superscript 2 plus sign in period 6, and R a superscript 2 plus sign in period 7. Group six contains C r superscript 3 plus sign and C r superscript 6 plus sign in period 4. Group seven contains M n superscript 2 plus sign in period 4. Group eight contains F e superscript 2 plus sign and F e superscript 3 plus sign in period 4. Group nine contains C o superscript 2 plus sign in period 4. Group ten contains N i superscript 2 plus sign in period 4, and P t superscript 2 plus sign in period 6. Group 11 contains C U superscript plus sign and C U superscript 2 plus sign in period 4, A g superscript plus sign in period 5, and A u superscript plus sign and A u superscript 3 plus sign in period 6. Group 12 contains Z n superscript 2 plus sign in period 4, C d superscript 2 plus sign in period 5, and H g subscript 2 superscript 2 plus sign and H g superscript 2 plus sign in period 6. Group 13 contains A l superscript 3 plus sign in period 3. Group 14 contains C superscript 4 negative sign in period 2. Group 15 contains N superscript 3 negative sign in period 2, P superscript 3 negative sign in period 3, and A s superscript 3 negative sign in period 4. Group 16 contains O superscript 2 negative sign in period 2, S superscript 2 negative sign in period 3, S e superscript 2 negative sign in period 4 and T e superscript 2 negative sign in period 5. Group 17 contains F superscript negative sign in period 2, C l superscript negative sign in period 3, B r superscript negative sign in period 4, I superscript negative sign in period 5, and A t superscript negative sign in period 6. Group 18 contains H e in period 1, N e in period 2, A r in period 3, K r in period 4, X e in period 5 and R n in period 6.
The periodic table, showing the most common charges of monoatomic ions for selected elements. Some elements exhibit a regular pattern of ionic charge when they form ions.

To learn more about ionic bonding please check out the page on ionic bonding.

Many compounds do not contain ions but instead consist of neutral atoms being involved in covalent bonding (sharing of electrons to create molecular compounds (covalent compounds).

Whereas ionic compounds are usually formed when a metal and a nonmetal combine, covalent compounds are usually formed by a combination of nonmetals. Thus, the periodic table can help us recognize many of the compounds that are covalent. We can use the positions of a compound’s elements in the periodic table to predict whether it is ionic or covalent at this point in our study of chemistry.

To learn more about covalent bonding please check out the page on covalent bonding.

In ionic bonding above we saw that we can have a monoatomic ion (ion consisting of one atom). We can also have polyatomic ions, ions that consist of more than one atom. In a polyatomic ion, we have both covalent and ionic bonding present. To learn more about polyatomic ions please check out the page on polyatomic ions.